CLM: Activated carbon large adsorption capacity
Activated carbon large adsorption capacity
23 Sep 2021 in 04:58am
Physical method is to use carbon dioxide, water vapor or the mixture of both as activator, the carbonized carbon material and gas in the activation furnace at 500~1200℃ for carbon activation reaction, so that the pore size of the carbonized material to expand, the formation of activated carbon with porous microcrystalline structure.Gas activation method mainly includes carbonization and activation engineering.The so-called carbonization, refers to the low temperature (about 500℃) is small, the volatile coal tar molecules in the material and the thermal decomposition and curing process of asphalt, that is, to remove the volatile in advance, made suitable for the next step of activation with carbonization.
When the temperature is below 600℃, the specific surface area of carbonized material increases with the increase of temperature.When 600~900℃, the specific surface area reaches a certain value: 250~300 m2/g; when above1000℃, the specific surface area shrinks rapidly.
When the carbonization temperature is above 800℃, the reaction performance of carbonized compounds and activation gas gradually becomes weaker, so the carbonization temperature is generally below 1000℃. However, if the residual volatile content and thermal effect are taken into account, the most suitable temperature should be 600~700℃39].
The carbonized substance obtained from the carbonization process is placed in water vapor or a mixture of water vapor and combustion gas and heat treated at 800~1000℃, which is called the activation process.
The commonly used activation gases are carbon dioxide, water vapor, oxygen, etc., due to the oxidation reaction of these gases on the surface of the carbonized substance, eroding the carbonized substance, thus producing a rich porous structure.(2) Chemical method.
Chemical activation method is a method of preparing activated carbon by adding chemicals to the raw materials used or impregnation into the raw materials or carbonized materials, and then heating it at high temperature in inert gas.The chemicals used in chemical activation are generally dehydrating.The more commonly used activator is: inorganic acid varieties have phosphoric acid, sulfuric acid and boric acid, salt varieties have zinc chloride, calcium carbonate and potassium sulfate, alkali varieties have sodium hydroxide, potassium hydroxide, etc.
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When the temperature is below 600℃, the specific surface area of carbonized material increases with the increase of temperature.When 600~900℃, the specific surface area reaches a certain value: 250~300 m2/g; when above1000℃, the specific surface area shrinks rapidly.
When the carbonization temperature is above 800℃, the reaction performance of carbonized compounds and activation gas gradually becomes weaker, so the carbonization temperature is generally below 1000℃. However, if the residual volatile content and thermal effect are taken into account, the most suitable temperature should be 600~700℃39].
The carbonized substance obtained from the carbonization process is placed in water vapor or a mixture of water vapor and combustion gas and heat treated at 800~1000℃, which is called the activation process.
The commonly used activation gases are carbon dioxide, water vapor, oxygen, etc., due to the oxidation reaction of these gases on the surface of the carbonized substance, eroding the carbonized substance, thus producing a rich porous structure.(2) Chemical method.
Chemical activation method is a method of preparing activated carbon by adding chemicals to the raw materials used or impregnation into the raw materials or carbonized materials, and then heating it at high temperature in inert gas.The chemicals used in chemical activation are generally dehydrating.The more commonly used activator is: inorganic acid varieties have phosphoric acid, sulfuric acid and boric acid, salt varieties have zinc chloride, calcium carbonate and potassium sulfate, alkali varieties have sodium hydroxide, potassium hydroxide, etc.
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